trans-Tetrachloridobis(diphenylacetonitrile)platinum(IV)
نویسندگان
چکیده
In the title compound, [PtCl(4)(C(14)H(11)N)(2)], the Pt atom lies on an inversion center and has a distorted octa-hedral environment. The main geometric parameters are Pt-N = 1.960 (5) Å, and Pt-Cl = 2.3177 (12) and 2.3196 (12) Å. The N C bond is a typical triple bond [1.137 (7) Å]. The Pt-N C-C unit is almost linear, with Pt-N-C and N-C-C angles of 174.6 (4) and 177.1 (6)°, respectively.
منابع مشابه
cis-Tetrachloridobis(1H-imidazole-κN 3)platinum(IV)
In the title complex, cis-[PtCl(4)(C(3)H(4)N(2))(2)], the Pt(IV) ion lies on a twofold rotation axis and is coordinated in a slightly distorted octa-hedral geometry. The dihedral angle between the imidazole rings is 69.9 (2)°. In the crystal, mol-ecules are linked by N-H⋯Cl hydrogen bonds, forming a three-dimensional network.
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